MIT Envisions DIY Solar Cells Made From Grass Clippings

A modified type of dye sensitized solar cell, nothing new.
https://en.wikipedia.org/wiki/Dye-sensitized_solar_cell [wikipedia.org]

You can easily make those at home: Take a piece of conductive glass, coat it with titanium dioxide (yes, exactly the pigment used for white paint, I tried the commercial pigments myself), dip it into a dye (yes, I tried chlorophyll, these things were known at least 15 years ago, this is when I did it), put on a second piece of glass and fill with electrolyte.

I have made hundreds of those, you can do it at home it a toaster oven, google for "graetzel cell video".

This type of cell has several very serious issues:

1) The efficiency is very low

2) The cell uses a liquid organic electrolyte. Of course there are tons of problems with leakage, toxic solvents etc.
The electrolyte often breaks down from the light, you'll always have oxygen diffusion into the system and react with all the chemicals. It is extremely difficult to make anything organic that can withstand light. Have a look at your painted garden chairs after a few years in the sun.

3) The dye breaks down quickly. Make a simple test. Take a few grass clippings and put them into the sun. You'll notice that they change color from green to brown.
The reason is that the chlorophyll degrades very rapidly in the sun. Grass makes new chlorophyll all of the time.
4) Titanium dioxide (and zinc oxide as well) are highly reactive materials under illumination. This is why you use them as white pigments. The sunlight creates free electrons, and those decompose a lot of the dirt in contact with the stuff. A white wall in the suns cleans itself to a large part.
Of course, you'll have the same effect in the solar cell, the TiO2 will act as a catalyst and degrade dye and electrolyte.

Make a simple test at home: Take a wall painted with titanium or zinc white. Dissolve some grass clippings in alcohol and spray the green stuff on the wall. Expose to sunlight and see how quickly it bleaches.

As a scientist myself, I find it very sad and unprofessional, how MIT is lying to the public.
A statement like
"If all goes well, in a few years it should be possible to gather up a pile of grass clippings, mix it with a blend of cheap chemicals, paint it on your roof and begin producing electricity. Talk about redefining green power plants!"
is very misleading, unethical and close to being a scientific fraud. Of course, you could never paint it on, how are you going to put on the electrodes?

Source: http://rss.slashdot.org/~r/Slashdot/slashdotScience/~3/st1MScwPR04/mit-envisions-diy-solar-cells-made-from-grass-clippings

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